LIGAND EFFECTS ON THE AEROBIC OXIDATION OF CYCLOHEXENE CATALYZED BY AQUA(PHOSPHINE)RUTHENIUM(II) COMPLEXES

被引：11

作者：

BESSEL, CA ^{[1
]}

LEISING, RA ^{[1
]}

TAKEUCHI, KJ ^{[1
]}

机构：

[1] SUNY BUFFALO,DEPT CHEM,BUFFALO,NY 14260

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 12期

关键词：

D O I：

10.1039/c39910000833

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The multistep nature of the aerobic oxidation of cyclohexene catalysed by a series of aqua(phosphine)ruthenium(ll) complexes can clearly be demonstrated from the correlation of catalyst turnovers with the rate constants of ligand substitution, and the correlation of catalyst turnovers with Hammett sigma-p values.

引用

页码：833 / 835

页数：3

共 10 条

[1] OXIDATION OF ORGANIC SUBSTRATES CATALYZED BY TRANS-[RUIII(1,10-PHENANTHROLINE)2(OH)(OH2)][CIO4]2 AND TRANS-[RUIII(2,2'-BYPYRIDINE)2(OH)(OH2)][CIO4]2
CHE, CM
LEUNG, WH
POON, CK
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (03) : 173 - 175
[2] ALKANE OXIDATIONS BY A NOVEL MU-3-OXO TRINUCLEAR RUTHENIUM CARBOXYLATE COMPLEX
DAVIS, S
DRAGO, RS
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (03) : 250 - 251
[3] COORDINATION OF STYRENE OXIDE TO A STERICALLY HINDERED RUTHENIUM(II) PORPHYRIN
GROVES, JT
HAN, YZ
VANENGEN, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (05) : 436 - 437
[4] LIGAND SUBSTITUTION STUDIES OF AQUO(PHOSPHINE)RUTHENIUM(II) COMPLEXES
LEISING, RA
OHMAN, JS
TAKEUCHI, KJ
[J]. INORGANIC CHEMISTRY, 1988, 27 (21) : 3804 - 3809
[5] AEROBIC OXIDATION OF CYCLOHEXENE WITH A PHOSPHINE RUTHENIUM(II) AQUO CATALYST
LEISING, RA
TAKEUCHI, KJ
[J]. INORGANIC CHEMISTRY, 1987, 26 (26) : 4391 - 4393
[6] MARCH J, 1985, ADV ORGANIC CHEM
[7] AN EXTENDED TABLE OF HAMMETT SUBSTITUENT CONSTANTS BASED ON THE IONIZATION OF SUBSTITUTED BENZOIC ACIDS
MCDANIEL, DH
BROWN, HC
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1958, 23 (03) : 420 - 427
[8] Sheldon R. A., 1981, METAL CATALYZED OXID
[9] SYKES P, 1986, GUIDEBOOK MECH ORGAN, P358
[10] STERIC EFFECTS OF PHOSPHORUS LIGANDS IN ORGANOMETALLIC CHEMISTRY AND HOMOGENEOUS CATALYSIS
TOLMAN, CA
[J]. CHEMICAL REVIEWS, 1977, 77 (03) : 313 - 348

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