SYNTHESIS OF TETRATHIAFULVALENE CHALCONES - RC(=O)CH=C(CH3)TTF, TTFC(=O)CH=C(CH3)R (R=TTF-C6H3S4 BCT-C6H5CR(CO)3 FC-C5H4FEC5H5) - CONDUCTIVITY OF A NEW CHARGE-TRANSFER COMPLEX TTFC(=O)CH=C(CH3)TTF-BULLET-TCNQ

被引：5

作者：

BESANCON, J ^{[1
]}

RADECKISUDRE, A ^{[1
]}

SZYMONIAK, J ^{[1
]}

PADIOU, J ^{[1
]}

机构：

[1] LAB CHIM MINERALE B, F-35700 RENNES, FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 429卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)83183-I

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel chalcones that contain tetrathiafulvalene (TTF) and/or metallocene (ferrocenyl or benchrotrenyl) moieties: RC(=O)CH=C(CH3)R' (R and/or R' = TTF: C6H3S4; Fc: C5H4FeCH5; Bct: C6H5Cr(CO)3) were prepared using TiCl3/Et3N as the condensation reagent. The 1-1 charge transfer complex with TCNQ (tetracyanoquinodimethane) was obtained for the ditetrathiafulvalenic derivative (R = R' = TTF). This complex exhibits the semiconducting behaviour.

引用

页码：335 / 344

页数：10

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