ELECTROCHEMICAL DETECTION OF SACCHARIDES BY THE REDOX CYCLE OF A CHIRAL FERROCENYLBORONIC ACID-DERIVATIVE - A NOVEL METHOD FOR SUGAR SENSING

被引：83

作者：

ORI, A ^{[1
]}

SHINKAI, S ^{[1
]}

机构：

[1] RES DEV CORP JAPAN,ERATO,CHEMIRECOGNICS PROJECT,KURUME,FUKUOKA 830,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 17期

关键词：

D O I：

10.1039/c39950001771

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chiral ferrocenylboronic acid 1 bearing an intramolecular tertiary amine binds saccharides at ca. pH 7, the complexation event, which can be Conveniently detected by an electrochemical method, shows chiral discrimination. for certain linear saccharides.

引用

页码：1771 / 1772

页数：2

共 12 条

[1] A SPECTROPHOTOMETRIC INVESTIGATION OF THE INTERACTION OF IODINE WITH AROMATIC HYDROCARBONS [J].

BENESI, HA ;

HILDEBRAND, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (08) :2703-2707

[2]

CHARLTON SC, 1992, Patent No. 316762

[3]

JAMES TD, 1994, ANGEW CHEM INT EDIT, V33, P2207, DOI 10.1002/anie.199422071

[4] NOVEL PHOTOINDUCED ELECTRON-TRANSFER SENSOR FOR SACCHARIDES BASED ON THE INTERACTION OF BORONIC ACID AND AMINE [J].

JAMES, TD ;

SANDANAYAKE, KRAS ;

SHINKAI, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (04) :477-478

[5] CHIRAL DISCRIMINATION OF MONOSACCHARIDES USING A FLUORESCENT MOLECULAR SENSOR [J].

JAMES, TD ;

SANDANAYAKE, KRAS ;

SHINKAI, S .

NATURE, 1995, 374 (6520) :345-347

[6] ARENEBORONATES FROM DIOLS AND POLYOLS [J].

KUIVILA, HG ;

KEOUGH, AH ;

SOBOCZENSKI, EJ .

JOURNAL OF ORGANIC CHEMISTRY, 1954, 19 (05) :780-783

[7] POLYOL COMPLEXES AND STRUCTURE OF THE BENZENEBORONATE ION [J].

LORAND, JP ;

EDWARDS, JO .

JOURNAL OF ORGANIC CHEMISTRY, 1959, 24 (06) :769-774

[8] STEREOSELECTIVE SYNTHESES .5. CORRELATION OF CENTRAL AND PLANAR CHIRALITY IN FERROCENE DERIVATIVES [J].

MARQUARDING, D ;

KLUSACEK, H ;

GOKEL, G ;

HOFFMANN, P ;

UGI, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (18) :5389-+

[9] EVIDENCE FOR MONODENTATE AND BISDENTATE BORONATE COMPLEXES OF GLUCOSE IN THE FURANOSE FORM - APPLICATION OF (1)J(C-C)-COUPLING-CONSTANTS AS A STRUCTURAL PROBE [J].

NORRILD, JC ;

EGGERT, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (05) :1479-1484

[10]

RUSSELL AP, 1991, Patent No. 4488

← 1 2 →