ANODIC CYANATIONS OF AROMATIC COMPOUNDS

被引：202

作者：

ANDREADE.S

ZAHNOW, EW

机构：

[1] Central Research Department, Experimental Station, E. I. du Pont de Nemours and Company, Wilmington

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 15期

关键词：

D O I：

10.1021/ja01043a028

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemical oxidations of cyanide ion solutions containing aromatic substrates result in three types of cyanation reaction: aromatic substitution of hydrogen; replacement of aromatic methoxyl by nitrile; and introduction of a nitrile group in an α position of tertiary amines. Mechanistic evidence indicates all products are derived from initial oxidation of aromatic substrate and subsequent reaction with cyanide ion. The fate of electrochemically generated cyano radical was investigated by esr spectroscopy. © 1969, American Chemical Society. All rights reserved.

引用

页码：4181 / +

页数：1

共 67 条

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[5] AMINE OXIDATION .3. A TEST REACTION FOR THE DEHYDROGENATION OF TRIETHYLAMINE - THE REACTIONS OF SOME TERTIARY AMINES WITH BENZOYL PEROXIDE
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BOWERS, VA
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