ABSORPTION SPECTRA OF URANIUM(III) AND URANIUM(IV) IN DClO(4) SOLUTION

被引：92

作者：

Cohen, Donald ^{[1
]}

Carnall, W. T. ^{[1
]}

机构：

[1] Argonne Natl Lab, Argonne, IL 60439 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1960年 / 64卷 / 12期

关键词：

D O I：

10.1021/j100841a031

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The absorption spectra of U(III) and U(IV) in DClO(4) has been observed from 0.2 to 2.6 mu. Solutions of a pure valence state were prepared and maintained by electrolytic reduction in a combination electrolysis-absorption cell. Several new bands have been discovered in the ultraviolet and near infrared regions, and their positions as well as those of the other bands in the spectra are compared with the energy levels calculated from theory.

引用

页码：1933 / 1936

页数：4

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