BIMOLECULAR RADICAL FORMATION THROUGH H-TRANSFER .3. TRANSFER HYDROGENATION AND DEUTERATION OF BUCKMINSTERFULLERENE C-60 BY 9,10-DIHYDROANTHRACENE AND 9,9',10,10'[D(4)]DIHYDROANTHRACENE

被引:136
作者
RUCHARDT, C
GERST, M
EBENHOCH, J
BECKHAUS, HD
CAMPBELL, EEB
TELLGMANN, R
SCHWARZ, H
WEISKE, T
PITTER, S
机构
[1] UNIV FREIBURG,FAK ORGAN CHEM,W-7800 FREIBURG,GERMANY
[2] FREIBURGER MAT FORSCHUNGSZENTRUM,FREIBURG,GERMANY
[3] TECH UNIV BERLIN,INST ORGAN CHEM,W-1000 BERLIN 12,GERMANY
[4] UNIV HEIDELBERG,INST ANORGAN CHEM,W-6900 HEIDELBERG,GERMANY
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 04期
关键词
D O I
10.1002/anie.199305841
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An efficient and simple method for the synthesis of two uniform buckminsterfullerene hydrogenation products, C60H18 and C60H36, is offered by the title reaction. The picture on the right shows a probable structure of C60H36 obtained from MM2 calculations. These results are an important step on the way to preparative organic chemistry with C60. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany
引用
收藏
页码:584 / 586
页数:3
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