INTRAMOLECULAR CHARGE-TRANSFER PROCESSES IN RESTRICTED ENVIRONMENTS

被引:11
作者
BHATTACHARYYA, K
机构
[1] Physical Chemistry Department Indian Association for the Cultivation of Science Jadavpur, Calcutta
关键词
D O I
10.1016/0167-7322(93)80050-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effect of environment on the dynamics of intramolecular charge transfer (ICT) processes has been discussed. It has been shown that the concept of polarity dependent rate of twisted ICT (TICT) process is applicable to a wide variety of molecules. Further, several restricted environments are found to influence the TICT processes markedly. The extraordinary sensitivity of the TICT processes has been utilised to probe ''local'' polarity of these restricted environments.
引用
收藏
页码:115 / 125
页数:11
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