REGIOSELECTIVITY IN METALATION REACTIONS OF 2-(2'-NAPHTHYL) PYRIDINE - 1'-REACTIVITY VERSUS 3'-REACTIVITY IN MERCURATION AND PALLADATION REACTIONS - CRYSTAL-STRUCTURE OF CHLORO(PYRIDINE) [2-(2'-PYRIDINYL)NAPHTHYL-C-3,N]PALLADIUM

被引：16

作者：

FORD, A ^{[1
]}

SINN, E ^{[1
]}

WOODWARD, S ^{[1
]}

机构：

[1] UNIV HULL,SCH CHEM,KINGSTON HULL HU6 7RX,YORKS,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 493卷 / 1-2期

关键词：

MERCURY; PALLADIUM; CYCLOMETALATION; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)05367-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Regioselectivity is found to vary with the reagent in cyclometallation reactions of 2-(2'-naphthyl)pyridine. Mercuration produces a mixture of 1'- and 3'-naphthyl metallated species with the 1'-substituted material as the major product. Palladation results in clean 3'-naphthyl metallation, as confirmed by the crystal structure of the pyridine derivative chloro(pyridine)[2-(2'-pyridinyl)naphthyl-C-3,N]palladium.

引用

页码：215 / 220

页数：6

共 29 条

[1] 2-PYRIDYL-2-YL-FUNCTIONALIZED AND QUINOLIN-2-YL-FUNCTIONALIZED ORGANYLTELLURIUM LIGANDS - THE STABILIZATION OF DIORGANYL TRITELLURIDES - THE CRYSTAL AND MOLECULAR-STRUCTURES OF 2-(2-PYRIDYL)PHENYLTELLURIUM(IV) TRIBROMIDE, DIMETHYLDITHIOCARBAMATO[2-(2-PYRIDYL)PHENYL]TELLURIUM(II), AND PARA-ETHOXYPHENYL 2-(2-PYRIDYL)PHENYL TELLURIDER [J].