SPIN-ORBIT AUTOIONIZATION AND INTENSITIES IN THE DOUBLE-RESONANT DELAYED PULSED-FIELD THRESHOLD PHOTOIONIZATION OF HCL

被引：19

作者：

ZHU, YF

GRANT, ER

WANG, KH

MCKOY, V

LEFEBVREBRION, H

机构：

[1] CALTECH,ARTHUR AMOS NOYES LAB CHEM PHYS,PASADENA,CA 91125

[2] UNIV PARIS 11,PHOTOPHYS MOLEC LAB,F-91405 ORSAY,FRANCE

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 12期

关键词：

D O I：

10.1063/1.466717

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

State-selected delayed pulsed-field threshold photoionization spectra of HCl and DCl are recorded in double-resonant transitions through the F (1) Delta, E (1) Sigma(+), and g (3) Sigma(-) states of the 4p pi Rydberg configuration. Comparison of observed rotational line strengths with calculated spectra, as well as with available time-of-flight photoelectron spectra, provides useful insight on the influence of spin-orbit and rotational autoionization on delayed pulsed-field threshold photoionization of HCl. Spin-orbit and rotational autoionization are seen to dramatically reduce the ion rotational intensity associated with the upper spin-orbit level of the ion.

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页码：8633 / 8640

页数：8

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