INFLUENCE OF MICROSTRUCTURE ON THE STRENGTH OF REACTION BONDED SILICON-NITRIDE (RBSN)

The effect of the microstructure of reaction bonded silicon nitride on strength is examined. The morphologies of the various microconstituents (α-matte, β-spikes, residual silicon and porosity) each play a role in determining the strength of the material. While density and hence percent porosity greatly affect strength, it is shown that the pore size and pore size distribution affect strength with equal importance. By minimizing the pore size and distribution and maximizing the α β ratio, a reaction bonded material (2.4 kg/m3) has been produced with a room temperature modulus of rupture (three point bending) of 297 MPa from a low green density starting material (1.5kg/m3). © 1979.