On the virial expansion treatment of physical arsorption

被引：17

作者：

Pierotti, R. A. ^{[1
]}

机构：

[1] Georgia Inst Technol, Sch Chem, Atlanta, GA 30332 USA

来源：

CHEMICAL PHYSICS LETTERS | 1968年 / 2卷 / 06期

关键词：

D O I：

10.1016/0009-2614(68)80033-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A statistical mechanical theory of solutions is used to obtain an expression for the adsorption potential and for the Gibbs isotherm equation. A virial expansion is developed and its coefficients are shown to be dependent upon a "potential of average force", as in the McMillan-Mayer theory of solutions. The treatment is valid for non-porous, porous and swelling substrates.

引用

页码：385 / 388

页数：4

共 16 条

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