FORMATION OF AROMATIC RADICAL-CATIONS BY OXIDATION WITH ELECTRO-NEGATIVELY SUBSTITUTED QUINONES IN ACID-MEDIA - KINETICS AND MECHANISM

被引：20

作者：

SEP, WJ ^{[1
]}

VERHOEVEN, JW ^{[1
]}

DEBOER, TJ ^{[1
]}

机构：

[1] UNIV AMSTERDAM,ORGAN CHEM LAB,NL-1018 WS AMSTERDAM,NETHERLANDS

来源：

TETRAHEDRON | 1979年 / 35卷 / 18期

关键词：

D O I：

10.1016/0040-4020(79)87034-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Electronegatively substituted quinones are shown to oxidize electronrich aromatic molecules to the corresponding radical-cations in acid medium via a reversible two step mechanism. The influence of acid strength on the rate of the reaction suggests that a protonated quinone molecule acts as the primary electron acceptor. The rate of formation of the radical cations depends on the one electron oxidation potential of the parent aromatic molecules in a way typical for endothermic outersphere electrontransfer. © 1979.

引用

页码：2161 / 2168

页数：8

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