STRUCTURAL CHARACTERIZATION OF A DIALKYLGALLIUM CATION - X-RAY CRYSTAL-STRUCTURE OF [ME2GA(TERT-BUNH2)2]BR

被引：17

作者：

ATWOOD, DA

JONES, RA

COWLEY, AH

BOTT, SG

ATWOOD, JL

机构：

[1] UNIV TEXAS,DEPT CHEM,AUSTIN,TX 78712

[2] UNIV ALABAMA,DEPT CHEM,TUSCALOOSA,AL 35487

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 425卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0022-328X(92)80037-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The X-ray crystal structure of [Me2Ga(tBuNH2)2]Br (1) has been determined. The compound was prepared in a 51% yield via the reaction of t-BuNH2 with Me2GaBr in Et2O solution. The solid state of 1 consists of [Me2Ga(tBuNH2)2[+ cations and bromide anions. The gallium cation adopts a highly distorted tetrahedral geometry with Me(1)-Ga-Me(2) and N(1)-Ga-N(2) angles of 121.5(5) and 95.6(3)-degrees, respectively.

引用

页码：C1 / C3

页数：3

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