PRODUCT FORMATION FROM THE GAS-PHASE REACTIONS OF OH RADICALS AND O-3 WITH BETA-PHELLANDRENE

被引：22

作者：

HAKOLA, H

SHOREES, B

AREY, J

ATKINSON, R

机构：

[1] UNIV CALIF RIVERSIDE,STATEWIDE AIR POLLUT RES CTR,RIVERSIDE,CA 92521

[2] UNIV CALIF RIVERSIDE,DEPT SOIL & ENVIRONM SCI,RIVERSIDE,CA 92521

来源：

ENVIRONMENTAL SCIENCE & TECHNOLOGY | 1993年 / 27卷 / 02期

关键词：

D O I：

10.1021/es00039a006

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

4-Isopropyl-2-cyclohexen-1-one was identified as a product of the gas-phase reactions of beta-phellandrene with OH radicals (in the presence of NO(x)) and with ozone, and formation yields of 0.29 +/- 0.07 and 0.29 +/- 0.06, respectively, were determined. Sampling several 500-L volumes from the reaction chamber onto polyurethane foam solid adsorbent, followed by solvent extraction and HPLC cleanup, gave sufficient product for identification by H-1 NMR.

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页码：278 / 283

页数：6

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