DESIGN OF COMPLEX-LIGAND SYSTEMS BASED ON THIOURACIL - A NOVEL CYCLIC TETRAMER OF COBALT(III) WITH 1-(2-THIOURACIL-4-METHYLENE)-3,6-DIAZAHEXANE

被引：17

作者：

KAJIWARA, T

ITO, T

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 15期

关键词：

D O I：

10.1039/c39940001773

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Schiff base derived from 2-thiouracil-4-aldehyde and dien reacts with COII (CF3SO3)(2) to afford a novel cyclic tetramer of cobalt(III) by self-assembly; the complex has a columnar cavity at its centre with an effective diameter of ca. 1.8 Angstrom.

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页码：1773 / 1774

页数：2

相关论文

共 15 条

[1] X-RAY CRYSTAL-STRUCTURE OF THE ACETONE SOLVATE OF TRIS(4,6-DIMETHYLPYRIMIDINE-2-THIONATO)COBALT(III) - COMPLEX INVOLVING 3 4-MEMBERED RINGS WITH NITROGEN AND SULFUR AS DONOR ATOMS [J].

CARTWRIGHT, BA ;

LANGGUTH, PO ;

SKAPSKI, AC .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (JAN) :63-67

[2] A DODECAHEDRAL, 8-COORDINATE CHELATE COMPLEX, TETRAKIS(2-MERCAPTOPYRIMIDINATO)TUNGSTEN(IV) [J].

COTTON, FA ;

ILSLEY, WH .

INORGANIC CHEMISTRY, 1981, 20 (02) :614-616

[3]

FOYE WO, 1972, J PHARM SCI, V8, P1209

[4] GENERALIZING THE METALLACROWN ANALOGY - LIGAND VARIATION AND SOLUTION STABILITY OF THE (V(V)O) 9-METALLACROWN-3 STRUCTURE TYPE [J].

GIBNEY, BR ;

STEMMLER, AJ ;

PILOTEK, S ;

KAMPF, JW ;

PECORARO, VL .

INORGANIC CHEMISTRY, 1993, 32 (26) :6008-6015

[5] COMPLEXES OF 1,4,6-TRIMETHYLPYRIMIDINE-2-THIONE WITH SOME DIVALENT METAL-HALIDES [J].

GOODGAME, DML ;

LEACH, GA .

INORGANICA CHIMICA ACTA, 1979, 32 (01) :69-73

[6] VERSATILITY OF COORDINATION BEHAVIOR OF 1-METHYLPYRIMIDINE-2-THIONE TOWARDS METAL-IONS OF 1ST TRANSITION SERIES [J].

GOODGAME, DML ;

LEACH, GA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (12) :1705-1709

[7] Researches on pyrimidines. CXXII. Improved methods for the synthesis of orotic acid [J].

Johnson, TB ;

Schroeder, EF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1931, 53 (02) :1989-1998

[8] Researches on pyridines LXXXVIII The synthesis of cytosine aldehyde [J].

Johnson, TB ;

Mikeska, LA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1919, 41 :810-817

[9] A MOLECULAR-BASED MAGNET WITH A FULLY INTERLOCKED 3-DIMENSIONAL STRUCTURE [J].

STUMPF, HO ;

OUAHAB, L ;

PEI, Y ;

GRANDJEAN, D ;

KAHN, O .

SCIENCE, 1993, 261 (5120) :447-449

[10] ZEOLITIC AND LAYERED MATERIALS [J].

SUIB, SL .

CHEMICAL REVIEWS, 1993, 93 (02) :803-826