SYNTHESIS AND CHARACTERIZATION OF THIOLATO-BRIDGED TITANIUM-PLATINUM AND TITANIUM-PALLADIUM HETEROBINUCLEAR COMPLEXES - MOLECULAR-STRUCTURE OF [(ETA(5)-C(5)H(4)SIME(3))(2)TI(MU-SPH)(2)PD(C6F5)(2)]

被引：36

作者：

AMADOR, U

DELGADO, E

FORNIES, J

HERNANDEZ, E

LALINDE, E

MORENO, MT

机构：

[1] UNIV AUTONOMA MADRID,FAC CIENCIAS,DEPT QUIM INORGAN,E-28049 MADRID,SPAIN

[2] UNIV COMPLUTENSE MADRID,FAC CIENCIAS QUIM,DIFRACC RAYOS X LAB,E-28040 MADRID,SPAIN

[3] INST CIENCIA MAT ARAGON,DEPT QUIM INORGAN,E-50009 ZARAGOZA,SPAIN

[4] UNIV LA RIOJA,DEPT QUIM,E-26001 LOGRONO,SPAIN

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 21期

关键词：

D O I：

10.1021/ic00125a029

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of titanium-platinum and -palladium heterobinuclear compounds with double thiolato bridges, [(eta(5)C(5)H(4)R')(2)Ti(mu-SR)(2)M(C6F5)(2)] (R' = H, SiMe(3); R = Ph, C6F5; M = Pd, Pt), has been prepared. The crystal structure of [(eta(5)-C(5)H(4)SiMe(3))(2)Ti(mu-SPh)(2)Pd(C6F5)(2)] has been established by single-crystal X-ray crystallography: the complex crystallizes in the monoclinic system in space group P2(1)/c; a = 10.237 (2) Angstrom; b = 14.635 (3) Angstrom; c = 27.651 (6) Angstrom; beta = 90.83 (2)degrees; Z = 4; and R = 0.056. The titanium atom is in pseudotetrahedral coordination environment, whereas the palladium is square-planar. The phenyl groups on the sulfur atoms adopt an endo (syn) arrangement with respect to the central Ti-S-2-Pd core.

引用

收藏

页码：5279 / 5284

页数：6

相关论文

共 65 条

[1] THE STEREODYNAMICS OF METAL-COMPLEXES OF SULFUR-CONTAINING, SELENIUM-CONTAINING, AND TELLURIUM-CONTAINING LIGANDS [J].

ABEL, EW ;

BHARGAVA, SK ;

ORRELL, KG .

PROGRESS IN INORGANIC CHEMISTRY, 1984, 32 :1-118

[2] PREPARATION OF PHENYLPLATINUM-ZIRCONIUM COMPLEXES WITH PH2PC5H4 OR PHP(C5H4)2 BRIDGING LIGANDS AND THEIR REACTIONS WITH CARBON-MONOXIDE [J].

ANDERSON, GK ;

LIN, MR .

ORGANOMETALLICS, 1988, 7 (11) :2285-2288

[3]

BAKER RTK, 1986, STRONG METAL SUPPORT

[4] SYNTHESIS OF AN EARLY-LATE HETEROBIMETALLIC IMIDO COMPLEX - COOPERATIVE REACTIVITY WITH N-H, O-H, AND S-H BONDS AND FORMATION OF A NOVEL AMINOPHOSPHINE COMPLEX [J].

BARANGER, AM ;

HOLLANDER, FJ ;

BERGMAN, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (17) :7890-7891

[5] UNUSUAL BRIDGING OF THE METAL CENTERS IN A HETEROMETALLIC TITANIUM PLATINUM COMPLEX - X-RAY STRUCTURE OF [CP2TI(MU-2-ETA-1-CC-T-BU)2PT(C6F5)2].CH2CL2 [J].

BERENGUER, JR ;

FALVELLO, LR ;

FORNIES, J ;

LALINDE, E ;

TOMAS, M .

ORGANOMETALLICS, 1993, 12 (01) :6-7

[6] THIOLATO-COMPLEXES OF THE TRANSITION-METALS [J].

BLOWER, PJ ;

DILWORTH, JR .

COORDINATION CHEMISTRY REVIEWS, 1987, 76 :121-185

[7] HETERONUCLEAR TRANSITION-METAL COMPLEXES .1. DI-MU-ORGANOTHIO(BIS-PI-CYCLOPENTADIENYLTITANIUM)TETRACARBONYL COMPLEXES OF GROUP-VI, (PI-C5H5)2TI(SR)2M(CO)4 [J].

BRATERMAN, PS ;

WILSON, VA ;

JOSHI, KK .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (01) :191-+

[8] COMPLEXES CONTAINING HETERONUCLEAR METAL METAL BONDS, SOME RECENT ADVANCES 1980-81 .A. COMPOUNDS CONTAINING 2 DIFFERENT TRANSITION-METALS (EXCLUDING MIXED-METAL CLUSTERS) [J].

BRUCE, MI .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 242 (JAN) :147-204

[9] ENERGETICS OF METAL SULFUR BONDS IN THE COMPLEXES TI(ETA-5-C5H5)2(SC2H5)2, W(ETA-5-(5H5)2(SC2H5)2 AND W (ETA-5-C5H5)2(SC6H5)2 - MOLECULAR-STRUCTURE OF TI(ETA-5-C5H5)2(SC2H5)2 [J].

CALHORDA, MJ ;

CARRONDO, MAAFDT ;

DIAS, AR ;

FRAZAO, CF ;

HURSTHOUSE, MB ;

SIMOES, JAM ;

TEIXEIRA, C .

INORGANIC CHEMISTRY, 1988, 27 (14) :2513-2518

[10] BIS(ETA-5-CYCLOPENTADIENYL)BIS(METHANETHIOLATO)TITANIUM(IV), (ETA-5-C5H5)2TI(SCH3)2 [J].

CARRONDO, MAAFDT ;

JEFFREY, GA .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1983, 39 (JAN) :42-44

← 1 2 3 4 5 6 7 →