THE 4-CARBON ELONGATION OF ALDEHYDO SUGARS USING 2-(TRIMETHYLSILOXY)-FURAN - A BUTENOLIDE ROUTE TO HIGHER MONOSACCHARIDES

被引：43

作者：

CASIRAGHI, G ^{[1
]}

COLOMBO, L ^{[1
]}

RASSU, G ^{[1
]}

SPANU, P ^{[1
]}

机构：

[1] CNR,IST APPLICAZ TECN CHIM AVANZATE PROBLEMI AGROBIOL,I-07100 SASSARI,ITALY

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 09期

关键词：

D O I：

10.1021/jo00296a001

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-(Trimethylsiloxy)furan is an available nucleophilic four-carbon synthon that reacts with sugar aldehydes and imines in the presence of BF3 etherate, furnishing Y-C-glycosylated butenolides with very high diastereoselection. The title butenolides represent versatile homochiral candidates to be manipulated into higher carbon sugars. © 1990, American Chemical Society. All rights reserved.

引用

页码：2565 / 2567

页数：3

共 25 条

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