A KINETIC-STUDY OF THE EQUILIBRIUM BETWEEN DIOXYGEN MONOFLUORIDE AND DIOXYGEN DIFLUORIDE

被引：8

作者：

CAMPBELL, GM

机构：

[1] Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1990年 / 46卷 / 03期

关键词：

D O I：

10.1016/S0022-1139(00)82921-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The equilibrium among dioxygen monofluoride, dioxygen difluoride, and oxygen has been studied in the temperature range 286 to 195 K. Forward and reverse reaction rate constants were determined. An activation energy of 13 kcal/mole was found for both reactions. The equilibrium constant in the middle of the temperature range was found to be 21.5. The estimated heats of formation of O2F and O2F2 were +2.6 and +4.5 kcal/mole. © 1990.

引用

页码：357 / 366

页数：10

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[2]

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