LOCAL MASS-TRANSPORT EFFECTS IN THE FMOI LABORATORY ELECTROLYZER

被引:97
作者
BROWN, CJ
PLETCHER, D
WALSH, FC
HAMMOND, JK
ROBINSON, D
机构
[1] PORTSMOUTH POLYTECH,DEPT CHEM,PORTSMOUTH PO1 2DT,ENGLAND
[2] ICI CHEM & POLYMERS LTD,DEPT RES & DEV,RUNCORN WA7 4QD,CHESHIRE,ENGLAND
关键词
D O I
10.1007/BF01092609
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A number of patterns of segmented line electrodes have been manufactured using copper printed circuit board technology. These segmented electrodes have been used to investigate local mass transport effects in ICI's FM01-LC parallel plate electrolyser. It is shown that in the absence of a turbulence promoter the current distribution is uneven. Along the direction of electrolyte flow. a tertiary current distribution is observed. In addition, close to the cell entrance, an uneven current distribution occurs perpendicular to the direction of electrolyte flow, this reflects the design of the electrolyte distributor. With a turbulence promoter the current distribution is more even and the entry effects are much reduced. The turbulence promoter can, however, impose its own pattern on the current distribution perpendicular to the flow.
引用
收藏
页码:613 / 619
页数:7
相关论文
共 21 条
[1]  
BROWN CJ, 1991, DECHEMA MONOGRAPHS, V123, P299
[2]  
Coeuret F., 1993, ELEMENTS GENIE ELECT, V2nd
[3]   ELECTRODE CURRENT DISTRIBUTION IN A HYPOCHLORITE CELL [J].
CZARNETZKI, LR ;
JANSSEN, LJJ .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1989, 19 (05) :630-636
[4]  
DEIRIBARNE AP, 1970, ELECTROCHIM ACTA, V15, P1827
[5]   ON THE MECHANISM OF TRANSFER ENHANCEMENT BY EDDY PROMOTERS [J].
FOCKE, WW .
ELECTROCHIMICA ACTA, 1983, 28 (08) :1137-1146
[6]  
GOODRIDGE F, 1985, ICHEME S SER, V98, P61
[7]   AXIAL-DISPERSION IN PARALLEL CHANNEL ELECTROCHEMICAL-CELLS [J].
JANSSON, REW ;
MARSHALL, RJ .
ELECTROCHIMICA ACTA, 1982, 27 (07) :823-831
[8]  
Landau U, 1981, AICHE S S, V77, P75
[9]   ENHANCED MASS-TRANSFER IN ELECTROCHEMICAL CELLS USING TURBULENCE PROMOTERS [J].
LEITZ, FB ;
MARINCIC, L .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1977, 7 (06) :473-484
[10]  
Newman J., 2021, ELECTROCHEMICAL SYST, V4th, DOI [10.1007/978-94-007-2999-5_11, DOI 10.1007/978-94-007-2999-5_11]