CHEMISTRY OF SINGLET OXYGEN - ISOLATION AND CHARACTERIZATION OF A STABLE ALLENE OXIDE FROM A FULVENE ENDOPEROXIDE

被引：23

作者：

ERDEN, I

DRUMMOND, J

ALSTAD, R

XU, FP

机构：

[1] San Francisco State University, Department of Chemistry and Biochemistry, San Francisco

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 08期

关键词：

D O I：

10.1016/S0040-4039(00)91767-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Decomposition of the saturated endoperoxide derived from 6-t-butylfulvene at 100-degrees-C gives a stable allene oxide which was isolated and characterized by spectroscopy and chemical transformations. The thermal isomerization of the parent unsaturated system is also described and the decomposition mechanisms are discussed.

引用

页码：1255 / 1258

页数：4

共 19 条

[1] ADAM W, 1978, ANGEW CHEM, V90, P223
[2] 1,3-DI-T-BUTYLALLENE OXIDE . ISOLATION AND ISOMERIZATION TO TRANS-2,3-DI-T-BUTYLCYCLOPROPANONE
CAMP, RL
GREEN, FD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (26) : 7349 - &
[3] CHAN TH, 1976, TETRAHEDRON LETT, P3253
[4] CHAN TH, 1980, TETRAHEDRON, V36, P2289
[5] SYNTHESIS AND THERMAL REACTIVITY OF SOME 2,3-DIOXABICYCLO[2.2.1]HEPTANE MODELS OF PROSTAGLANDIN ENDOPEROXIDES
COUGHLIN, DJ
SALOMON, RG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (02) : 655 - 657
[6] PROSTAGLANDIN ENDOPEROXIDE NUCLEUS AND RELATED BICYCLIC PEROXIDES - SYNTHETIC AND SPECTROSCOPIC STUDIES
COUGHLIN, DJ
BROWN, RS
SALOMON, RG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (06) : 1533 - 1539
[7] ALLENE EPOXIDATION - ISOLATION OF REACTIVE INTERMEDIATES FROM HINDERED ALLENES
CRANDALL, JK
CONOVER, WW
KOMIN, JB
MACHLEDE.WH
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (12) : 1723 - 1729
[8] ERDEN I, 1987, TETRAHEDRON LETT, P3779
[9] PHOTOCHEMICAL OXIDATION OF FULVENE DERIVATIVES .5. ISOLATION AND PROPERTIES OF 6,6-DIMETHYLFULVENE 1,4-EPIDIOXIDE
HARADA, N
UDA, H
UENO, H
UTSUMI, S
[J]. CHEMISTRY LETTERS, 1973, (11) : 1173 - 1176
[10] HARADA N, 1971, J AM CHEM SOC, V94, P1777

← 1 2 →