WETTING OF ALUMINIUM OXIDE BY MOLTEN ALUMINIUM AND OTHER METALS

The sessile drop technique has been used to measure the contact angle of molten aluminium, aluminium-nickel and aluminium-copper alloys, copper and gold, with sapphire, ruby and recrystallised alumina. Measurements were made in vacuo, and as a function of time and temperature over the range 800 to 1500° C. Cinematography and time-lapse photography were used. At temperatures below 950° C, sessile drops of aluminium reached equilibrium only after a period of time which increased with decrease in temperature and could be in excess of one hour. A rapid increase in contact area occurred around 900° C. Above 1150° C drops of aluminium and of the aluminium alloys were observed to spread and contract repeatedly. Contractions were observed with both polycrystalline and single-crystal alumina, although they were much more pronounced with the latter, and were associated with the formation of a series of reaction rings on the plaque. Ruby and sapphire behaved similarly. The shape of the rings depended on the crystallographic orientation of the plaque: the reaction profile tended to terminate in certain low index directions. Neither contractions nor reaction was observed with copper or gold. The observations are discussed in terms of the combined effects of evaporation, chemical reactivity and interfacial tensions in the system. © 1969 Chapman and Hall.