PRESSURE TEMPERATURE PHASE-DIAGRAM OF SOLID AND LIQUID TE UNDER PRESSURES UP TO 10 GPA

被引:53
作者
BRAZHKIN, VV
VOLOSHIN, RN
POPOVA, SV
UMNOV, AG
机构
[1] Inst. of High Pressure Phys., Acad. of Sci., Troick
关键词
D O I
10.1088/0953-8984/4/6/006
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The P-T phase diagram of Te has been investigated by means of thermobaro-analysis (TBA) and electrical resistance measurements. For crystalline Te the boundary of the transition Te(III)-Te(IV) has been found and the location of triple point Te(III)-L'-Te(IV) has been established (P = 7.6 +/- 0.3 GPa; T = 835 +/- 15 K). The melting curve of Te was investigated up to 10 GPa. In the Te melt the transition L-L' has been found from the-TBA signal and by jumps in the electrical resistance. The triple point L-Te(III)-L' has been found to be located at P = 4.7 +/- 0.3 GPa and T = 800 +/- 15 K. At pressures lower than P = 1.6 +/- 0.4 GPa and temperatures higher than T = 1120 +/- 30 K the TBA anomalies and the jumps in resistance become smooth and unmeasurable. The model of a phase transition in a liquid is presented based on the existence of crystal-like clusters in the melt.
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页码:1419 / 1425
页数:7
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