CHEMILUMINESCENT CHARACTERISTICS OF SOME INDOLE-DERIVATIVES

被引：21

作者：

CHEN, GN

XU, XQ

DUAN, JP

HE, MM

ZHANG, F

机构：

来源：

ANALYST | 1995年 / 120卷 / 06期

关键词：

CHEMILUMINESCENCE; INDOLE DERIVATIVES; TRYPTOPHAN;

D O I：

10.1039/an9952001699

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The chemiluminescent behaviour of some indole derivatives in alkaline solution in the presence of Fe3+ was studied in detail. The effects of various kinds of surfactants and oxidants on the chemiluminescent reaction were studied. A how injection system with chemiluminescent detection was developed for the determination of tryptophan, and the effects of some inorganic ions and basic amino acids were examined, Based on the results of treatment with the Huckel molecular orbital method and the investigations of fluorescent and absorption spectra, the relationship between structural characteristics and chemiluminescent behaviour is discussed, and a possible mechanism for this chemiluminescent reaction is proposed.

引用

页码：1699 / 1704

页数：6

共 8 条

[1]

CHEN GN, 1994, ANAL CHIM ACTA, V292, P159

[2]

CJHEN GN, 1994, MICROCHIM ACTA, V116, P227

[3] CHEMILUMINESCENCE OF L-TRYPTOPHAN IN COPPER (II) - HYDROGEN-PEROXIDE - POTASSIUM-SODIUM TARTRATE SYSTEM [J].