NEW METHOD FOR THE PREPARATION OF ORTHO-ARYLOXYPHENOLS - PUMMERER-TYPE REARRANGEMENT OF AN OMICRON-HYDROXYARYL SULFOXIDE

被引：30

作者：

JUNG, ME

JACHIET, D

KHAN, SI

KIM, C

机构：

[1] Department of Chemistry and Biochemistry, University of California, Los Angeles

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 03期

关键词：

D O I：

10.1016/0040-4039(94)02270-L

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A facile two-step preparation of o-aryloxyphenols is described in which the key step is the intramolecular trapping of an alpha-keto sulfonium salt prepared by Pummerer rearrangement of a symmetrical o-hydroxyaryl sulfoxide to give an orthoquinone mono(monothioketal).

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页码：361 / 364

页数：4

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