ADSORPTIVE MECHANISM ON ACTIVATED CARBON IN THE LIQUID-PHASE .1. FREE-ENERGY CHANGE FOR ADSORPTION OF ORGANIC-COMPOUNDS FROM AQUEOUS-SOLUTION ON ACTIVATED CARBON

被引：46

作者：

ABE, I ^{[1
]}

HAYASHI, K ^{[1
]}

KITAGAWA, M ^{[1
]}

URAHATA, T ^{[1
]}

机构：

[1] SOC ACTIVATED CARBON RES, KITA KU, OSAKA 530, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1979年 / 52卷 / 07期

关键词：

D O I：

10.1246/bcsj.52.1899

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The adsorption isotherms, from aqueous solution onto activated carbon, have been determined for the 22 aliphatic monofunctional compounds; alcohols, carboxylic acids, ketones, ethers, esters, and aldehydes. The free energy change for the adsorption process has been calculated from the adsorption equilibrium constant at infinite dilution; a linear relationship exists between the free energy change and the number of carbon atoms in the solute. The free energy of adsorption has been divided into two contributions: the hydrocarbon and the functional group contribution. The free energy change for the adsorption process has been compared with the free energy change for the precipitation process from solution into the pure liquid solute.

引用

页码：1899 / 1904

页数：6

共 27 条

[1] Alexander A, 1949, COLLOID SCI, V1
[2] SOLUBILITY OF NONELECTROLYTES IN POLAR-SOLVENTS .2. SOLUBILITY OF ALIPHATIC-ALCOHOLS IN WATER
AMIDON, GL
YALKOWSKY, SH
LEUNG, S
[J]. JOURNAL OF PHARMACEUTICAL SCIENCES, 1974, 63 (12) : 1858 - 1866
[3] SOLUBILITY OF NONELECTROLYTES IN POLAR-SOLVENTS .5. ESTIMATION OF SOLUBILITY OF ALIPHATIC MONOFUNCTIONAL COMPOUNDS IN WATER USING A MOLECULAR SURFACE-AREA APPROACH
AMIDON, GL
YALKOWSKY, SH
ANIK, ST
VALVANI, SC
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1975, 79 (21) : 2239 - 2246
[4] DISTRIBUTION OF NORMAL-ALKANOIC ACIDS BETWEEN WATER AND NORMAL-ALKANES
AVEYARD, R
MITCHELL, RW
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1970, 66 (565P): : 37 - &
[5] THERMODYNAMICS OF ADSORPTION FROM SOLUTION .4. TEMPERATURE DEPENDENCE OF ADSORPTION
BARTELL, FE
THOMAS, TL
FU, Y
[J]. JOURNAL OF PHYSICAL AND COLLOID CHEMISTRY, 1951, 55 (09) : 1456 - 1462
[6] Dubinin M.M., 1971, ADVCHEMSER, V102, P69
[7] DUBININ MM, 1949, ZH FIZ KHIM+, V23, P469
[8] THE POTENTIAL THEORY OF ADSORPTION OF GASES AND VAPORS FOR ADSORBENTS WITH ENERGETICALLY NONUNIFORM SURFACES
DUBININ, MM
[J]. CHEMICAL REVIEWS, 1960, 60 (02) : 235 - 241
[9] DUBININ MM, 1947, ZH FIZ KHIM+, V21, P1351
[10] ADSORPTION AND PORE-SIZE MEASUREMENTS ON CHARCOALS AND WHETLERITES
EMMETT, PH
[J]. CHEMICAL REVIEWS, 1948, 43 (01) : 69 - 148

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