DIALKYLCARBAMATO COMPLEXES OF PALLADIUM (II) - CRYSTAL-STRUCTURE OF TRANS-[PD(O2CNET2)2(NHET2)2]

被引：28

作者：

ANILLO, A

DELLAMICO, DB

CALDERAZZO, F

NARDELLI, M

PELIZZI, G

ROCCHI, L

机构：

[1] UNIV PARMA,CNR,CTR STRUTT DIFFRATTOMETR,I-43100 PARMA,ITALY

[2] UNIV PISA,DIPARTIMENTO CHIM & CHIM IND,SEZ CHIM INORGAN,I-56126 PISA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1991年 / 11期

关键词：

D O I：

10.1039/dt9910002845

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Pd(MeCN)4][BF4]2 with NHR2 (R = Et or Pr(i)) and carbon dioxide in toluene led to the dialkylcarbamato complexes [Pd(O2CNR2)2(NHR2)2]. The derivative trans-[Pd(O2CNEt2)2(NHEt2)2] was studied by X-ray diffraction methods. The square-planar geometry of the palladium atom involves one oxygen atom of each monodentate carbamato group and two amine nitrogen atoms. An intramolecular N-H ... O bond is probably responsible for a further stabilization within the molecule, for the features of the IR bands associated with the carbamato ligand and for the H-1 NMR non-equivalence observed within the amine alkyl group at room temperature.

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页码：2845 / 2849

页数：5

相关论文

共 42 条

[1]

ANILLO A, 1989, GAZZ CHIM ITAL, V119, P653

[2]

BARNARD CFJ, 1987, COMPREHENSIVE COORDI, V5, P1112

[3] FORMATION OF ALKYLURETHANES FROM CARBON-DIOXIDE BY REGIOSELECTIVE O-ALKYLATION OF ALKALI-METAL N,N-DIETHYLCARBAMATES IN THE PRESENCE OF COMPLEXING AGENTS [J].

BELFORTE, A ;

CALDERAZZO, F .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (05) :1007-1009

[4] SYNTHESIS AND REACTIVITY OF N,N-DIALKYLCARBAMATO COMPLEXES OF MANGANESE(II) - CRYSTAL AND MOLECULAR-STRUCTURE OF [MN6(O2CNET2)12], A HEXAMER WITH 4 5-CO-ORDINATED MANGANESE(II) ATOMS [J].

BELFORTE, A ;

CALDERAZZO, F ;

ZANAZZI, PF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (12) :2921-2926

[5] SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURE OF NEW (N,N-DI-N-PROPYLTHIOCARBAMATO)PALLADIUM(II) COMPOUNDS [J].

BESENYEI, G ;

HERDTWECK, E ;

HOLLY, S ;

MANNIG, D ;

NOTH, H ;

SIMANDI, LI ;

VISKI, P .

INORGANIC CHEMISTRY, 1988, 27 (18) :3201-3206

[6] HYDRIDES OF PLATINUM(II) AND PLATINUM(IV) INCORPORATING HYDROGENSULFIDE AND HYDROGENSELENIDE LIGANDS [J].

BLACKLAWS, IM ;

EBSWORTH, EAV ;

RANKIN, DWH ;

ROBERTSON, HE .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (07) :753-758

[7] DIALKYL-CARBAMATE COMPLEXES OF TRANSITION-ELEMENTS .1. NEW METHOD FOR SYNTHESIS OF N,N-DIALKYL-CARBAMATE AND N,N-DIALKYLDITHIOCARBAMATO COMPLEXES OF URANIUM(IV) [J].

CALDERAZZO, F ;

DELLAMICO, G ;

NETTI, R ;

PASQUALI, M .

INORGANIC CHEMISTRY, 1978, 17 (02) :471-473

[8] DIALKYL-CARBAMATE COMPLEXES OF TRANSITION-ELEMENTS .2. CRYSTAL AND MOLECULAR-STRUCTURE OF DI-MU3-OXO-DODECA(DIETHYLCARBAMATO)TETRAURANIUM(IV) [J].

CALDERAZZO, F ;

DELLAMICO, G ;

PASQUALI, M ;

PEREGO, G .

INORGANIC CHEMISTRY, 1978, 17 (02) :474-479

[9]

Chatt J., 1956, SUOMEN KEMI B, V29, P75

[10] ISOLATION OF THE ANIONS [M(CO)5(SH)]- AND [M2(CO)10(MU-SH)]-(M=CR, MO, AND W) AS SALTS OF THE SODIUM (18-CROWN-6-ETHER) CATION - X-RAY-ANALYSIS OF THE SODIUM CARBONYL LINKED POLYMERIC STRUCTURES OF THE TUNGSTEN SPECIES [J].

COOPER, MK ;

DUCKWORTH, PA ;

HENRICK, K ;

MCPARTLIN, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1981, (12) :2357-2364

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