METAL-LIGAND ELECTRON TRANSFERS IN VANADIUM COMPLEXES OF 11-TUNGSTOSILICATE ISOMERS

被引：27

作者：

HERVE, G

TEZE, A

LEYRIE, M

机构：

[1] Laboratoire de Chimie des métaux de transition, Equipe de Recherche associee au CN.R.S n° 608, Université Pierre et Marie Curie, 75230 PARIS CEDEX 05, 4, place Jussieu

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1979年 / 9卷 / 04期

关键词：

D O I：

10.1080/00958977908073829

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(VSiW11O40)n−complexes exhibit two kinds of redox systems, those of vanadium [formula omitted] and those of the ligand. Electron transfers between the vanadium and the ligand are observed by change in the pH. Electronic spectra are discussed with regard to two types of electronic transitions, intervalence transfers and d-d transitions. © 1979, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：245 / 249

页数：5

共 10 条

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