ENTHALPIES OF SOLUTION AND OF CRYSTALLIZATION OF LITHIUM-NITRATE AND OF LITHIUM-NITRATE TRIHYDRATE IN WATER AT 25-DEGREES-C

被引:6
作者
WOLF, G
VACEK, V
PEKAREK, V
机构
[1] PRAGUE INST CHEM TECHNOL,DEPT CHEM ENGN,CS-16628 PRAGUE 6,CZECHOSLOVAKIA
[2] CZECHOSLOVAK ACAD SCI,INST INORGAN CHEM,CS-16000 PRAGUE 6,CZECHOSLOVAKIA
关键词
Activity coefficients; enthalpies of solution and hydration; enthalpy of crystallization; lithium nitrate; lithium nitrate trihydrate;
D O I
10.1007/BF00650506
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The enthalpies of crystallization of LiNO3 and LiNO3-3H2O from aqueous solutions at 25°C, measured by a calorimetric method and determined from the previously published data on the concentration dependence of the enthalpy of solution, are reported. The results are compared with the values obtained from the concentration dependences of the activity coefficients and from the temperature dependences of the solubilities. The enthalpy of solution at infinite dilution and the enthalpy of hydration are given. © 1990 Plenum Publishing Corporation.
引用
收藏
页码:1029 / 1039
页数:11
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