TRANSFORMATION OF 4-NITROALKANE-1,7-DIONES INTO PYRROLIZIDINES

被引：21

作者：

VAVRECKA, M ^{[1
]}

JANOWITZ, A ^{[1
]}

HESSE, M ^{[1
]}

机构：

[1] UNIV ZURICH,INST ORGAN CHEM,WINTERTHURERSTR 190,CH-8057 ZURICH,SWITZERLAND

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 40期

关键词：

D O I：

10.1016/0040-4039(91)80079-L

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Depending on the conditions the reduction of 5-nitropentadecane-2,8-dione (4) gave as main products the two isomeric pyrrolizidines 1a (xenovenine, NaBH3CN/NH4OAc; as N-15-1a with NaBH3CN/(NH4OAc))-N-15 and 1b (H-2-Pd/C), respectively.

引用

页码：5543 / 5546

页数：4

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