REACTION OF PERFLUOROALKYL IODIDES WITH ALKENES INITIATED BY ORGANOPHOSPHINE AND RELATED-COMPOUNDS

被引：35

作者：

HUANG, WY

ZHANG, HZ

机构：

[1] Shanghai Institute of Organic Chemistry, Academia Sinica, Shanghai

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1990年 / 50卷 / 01期

关键词：

D O I：

10.1016/S0022-1139(00)82185-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Perfluoroalkyl iodides reacted with alkenes in acetonitrile solution containing catalytic amounts of an organophosphine under mild conditions to give the corresponding adducts in moderate to high yields. Addition of hydroquinone to the reaction mixture suppressed the reaction. Diallyl ether reacted to afford tetrahydrofuran derivatives. These findings indicated that the reaction involved a free radical mechanism. © 1990.

引用

页码：133 / 140

页数：8

共 16 条

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