Intermolecular Interaction Revealed in the Crystal Structures of Chiral Smectogenic Biphenyl Esters

被引:15
作者
Hori, Kayak [1 ]
Ohashi, Yuji [2 ]
机构
[1] Ochanomizu Univ, Dept Chem, Bunkyo Ku, Tokyo 112, Japan
[2] Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 152, Japan
关键词
crystal structure; biphenyl esters; X-ray diffraction; chiral smectogens;
D O I
10.1080/00268949108046056
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Intermolecular interactions revealed in the crystal structures are discussed in terms of the lateral overlapping of the core moities and the arrangements of the polar groups for chiral smectogenic biphenyl esters. It is found that the packing modes of the molecules within a layer, which are closely related to the liquid crystal phase sequences, are dependent on the length of the moiety sandwiched by the two polar groups.
引用
收藏
页码:171 / 176
页数:6
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