CHEMICAL PROBLEMS OF THE MECHANISM OF ACTION OF THE CHLOROTHIOBENZAMIDES

被引：11

作者：

BAHADIR, M ^{[1
]}

NITZ, S ^{[1
]}

PARLAR, H ^{[1
]}

KORTE, F ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST CHEM,D-8050 MUNICH 2,FED REP GER

来源：

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 1979年 / 27卷 / 04期

关键词：

D O I：

10.1021/jf60224a017

中图分类号：

S [农业科学];

学科分类号：

09 ;

摘要：

Both the direct and the photoinduced oxidation reactions of chlorine-substituted thiobenzamides (1b-3e) have been investigated. Asymmetric chlorophenylthiadiazoles (4b-4e) were identified as the principal transformation products. Oxidation of 2, 6-dichlorothiobenzamide (le) with nitrous acid unexpectedly afforded the corresponding 2, 6-dichlorophenyl mustard oil (3e), which has a strongly enhanced herbicidal action. © 1979, American Chemical Society. All rights reserved.

引用

页码：815 / 818

页数：4

共 6 条

[1] NITRILE SULFIDES - SYNTHESIS OF 1,2,4-THIADIAZOLES [J].

HOWE, RK ;

FRANZ, JE .

JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (07) :962-964

[2]

KITAMURA R, 1937, YAKUGAKU ZASSHI, V57, P659

[3] REAKTIONEN MIT N-SULFINYLVERBINDUNGEN .3. 1.2.4-THIADIAZOLE N-ARYLSULFONYL-AMIDINE UND -GUANIDINE BEI UMSETZUNGEN MIT THIONVERBINDUNGEN . N-SULFINYLIERUNG VON HYDRAZIDEN [J].

KRESZE, G ;

HORN, A ;

PHILIPPS.R ;

TREDE, A .

CHEMISCHE BERICHTE-RECUEIL, 1965, 98 (10) :3401-&

[4]

LINSER H, 1956, 1955 P S WYE COLL, P141

[5] SYNTHESIS OF 1,2,4-THIADIAZOLES FROM NITRILES AND SULFUR [J].

MACK, W .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1967, 6 (12) :1084-&

[6]

WEGLER R, 1977, CHEM PFLANZENSCHUTZ, V5, P211

← 1 →