KINETIC-THEORY OF A PHOTOLYTICALLY DRIVEN HOT-ATOM REACTION

被引：4

作者：

JHON, MS ^{[1
]}

DAHLER, JS ^{[1
]}

机构：

[1] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 11期

关键词：

D O I：

10.1063/1.437324

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Kinetic theory is applied to reactions of atoms excited translationally by photolysis. Chosen as examples are the hot deuterium atoms produced by photolysis of DI. A kinetic equation is derived for the momentum distribution of these hot atoms. This equation incorporates the moderating effects of nonreactive collisions as well as the perturbations caused by the two extraction reactions D+H2→HD+H and D+DI→D2+I. Relationships are established between the solution of this kinetic equation and the rates of formation of the two product species HD and D2. Finally, several properties of this equation and of its solutions are examined. © 1979 American Institute of Physics.

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页码：5292 / 5295

页数：4

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