RHODIUM(I) CATALYZED DECOMPOSITION OF FORMIC-ACID

被引：78

作者：

STRAUSS, SH

WHITMIRE, KH

SHRIVER, DF

机构：

[1] Department of Chemistry, Northwestern University, Evanston

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 174卷 / 03期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0022-328X(00)85605-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Rh(C6H4PPh2)(PPh3)2 catalyzes the decomposition of formic acid to CO2 and H2. The initial step is the oxidative addition of formic acid to produce the intermediate Rh(HCO2)(PPh3)3, which probably is followed by β-hydride elimination, to produce CO2 and RhH(PPh3)3. The latter reacts with formic acid to produce H2 and to reform Rh(HCO2)(PPh3)3. © 1979.

引用

页码：C59 / C62

页数：4

共 26 条

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