DIASTEREOSELECTIVE CYCLIZATION OF ALLYSILANES ON ALPHA-ACYLIMINIUM IONS - A NEW APPROACH TO (+/-)-MYRTINE AND (+/-)-EPIMYRTINE

被引：34

作者：

GELASMIALHE, Y

GRAMAIN, JC

LOUVET, A

REMUSON, R

机构：

[1] Laboratoire de Chimie, Substances Naturelles associé au CNRS, Université Blaise Pascal (Clermont-II)

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 01期

关键词：

ALLYLSILANE; ACYLIMINIUM ION; MYRTINE; EPIMYRTINE;

D O I：

10.1016/S0040-4039(00)77676-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Total synthesis of (+/-)-myrtine and (+/-)-epimyrtine is described using an intramolecular allylsilane N-acyliminium ion cyclization.

引用

收藏

页码：73 / 76

页数：4

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