PH-RESPONSIVE MOLECULAR RECOGNITION BY A WATER-SOLUBLE CYCLOPHANE BEARING L-ASPARTATE MOIETIES

被引：9

作者：

KIKUCHI, J ^{[1
]}

EGAMI, K ^{[1
]}

SUEHIRO, K ^{[1
]}

MURAKAMI, Y ^{[1
]}

机构：

[1] KYUSHU UNIV, FAC ENGN, DEPT CHEM SCI & TECHNOL, HIGASHI KU, FUKUOKA 812, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 09期

关键词：

D O I：

10.1246/cl.1992.1685

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel water-soluble cyclophane host bearing four pH-sensitive tentacles was prepared from 1,6,20,25-tetraaza[6.1.6.1]paracyclophane and L-aspartic acid. The host was found to exist primarily as tetracationic and tetraanionic species in pH ranges below 1 and above 11, respectively, and to exhibit pH-responsive molecular recognition toward various aromatic guests.

引用

页码：1685 / 1688

页数：4

共 13 条

[1] COMPLEXATION OF TERT-BUTYLAMMONIUM PERCHLORATE BY CROWN ETHERS IN POLAR-SOLVENTS STUDIED BY H-1-NMR SPECTROSCOPY
DEBOER, JAA
REINHOUDT, DN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (19) : 5347 - 5351
[2] COMPLEXATION OF NEUTRAL MOLECULES BY CYCLOPHANE HOSTS
DIEDERICH, F
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (03): : 362 - 386
[3] CYCLOPHANES AS HOSTS FOR AROMATIC AND ALIPHATIC GUESTS
KOGA, K
ODASHIMA, K
[J]. JOURNAL OF INCLUSION PHENOMENA, 1989, 7 (01): : 53 - 60
[4] DREIDING - A GENERIC FORCE-FIELD FOR MOLECULAR SIMULATIONS
MAYO, SL
OLAFSON, BD
GODDARD, WA
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (26) : 8897 - 8909
[5] INCLUSION BEHAVIOR OF AZACYCLOPHANES HOLDING VARIOUS HYDROPHOBIC CAVITIES
MURAKAMI, Y
KIKUCHI, J
[J]. PURE AND APPLIED CHEMISTRY, 1988, 60 (04) : 549 - 554
[6] SYNTHESES OF MACROCYCLIC ENZYME MODELS .8. CONFORMATIONAL MOBILITY AND MOLECULAR RECOGNITION BY THE INTERNAL CAGE OF KYUPHANE
MURAKAMI, Y
KIKUCHI, J
OHNO, T
HIRAYAMA, T
HISAEDA, Y
NISHIMURA, H
SNYDER, JP
STELIOU, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (22) : 8229 - 8242
[7] PH-DEPENDENT MOLECULAR RECOGNITION PERFORMED BY A POLYCATIONIC CUBIC AZAPARACYCLOPHANE
MURAKAMI, Y
KIKUCHI, JI
OHNO, T
HIRAYAMA, T
NISHIMURA, H
[J]. CHEMISTRY LETTERS, 1989, (07) : 1199 - 1202
[8] MURAKAMI Y, 1990, ADV SUPRAMOLECULAR C, V1, P109
[9] MURAKAMI Y, 1991, FRONTIERS SUPRAMOLEC, P145
[10] INCLUSION COMPLEX-FORMATION IN A PARTICULAR GEOMETRY BY A WATER-SOLUBLE PARACYCLOPHANE IN AQUEOUS-SOLUTION - NMR-STUDIES
ODASHIMA, K
ITAI, A
IITAKA, Y
ARATA, Y
KOGA, K
[J]. TETRAHEDRON LETTERS, 1980, 21 (45) : 4347 - 4350

← 1 2 →