CONDUCTANCE STUDY OF COPPER(I) AND SILVER(I) SALTS OF SYMMETRICAL ANIONS IN ACETONITRILE

被引：73

作者：

YEAGER, HL

KRATOCHV, B

机构：

[1] Department of Chemistry, University of Alberta, Edmonton, Alta.

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 06期

关键词：

D O I：

10.1021/j100726a053

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Conductance measurements are reported for CuClO4, CuBF4, CuPF6, AgClO4, AgBF4, AgPF6, and AgNO3 in acetonitrile at 25°. Analysis by the Fuoss-Onsager theory indicates association for AgNO3, CuBF4, and CuPF6. Single-ion conductivities for Cu (I ), Ag (I ), NO3-, BF4-, and PF6- are calculated. The anion values can be explained on a crystallographic size basis, while those for Cu(I) and Ag(I) are interpreted in terms of specific solvation by acetonitrile.

引用

收藏

页码：1963 / +

页数：1

相关论文

共 22 条

[1] NONAQUEOUS SILVER NITRATE SOLUTIONS . SPECTRAL STUDIES IN ACETONITRILE [J].

BADDIEL, CB ;

TAIT, MJ ;

JANZ, GJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1965, 69 (10) :3634-&

[2] EVALUATION OF SINGLE ION CONDUCTIVITIES IN ACETONITRILE NITROMETHANE AND NITROBENZENE USING TETRAISOAMYLAMMONIUM TETRAISOAMYLBORIDE AS REFERENCE ELECTROLYTE [J].

COETZEE, JF ;

CUNNINGH.GP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (12) :2529-&

[3] PURIFICATION OF ACETONITRILE AS A SOLVENT FOR EXACT MEASUREMENTS [J].

COETZEE, JF ;

MCGUIRE, DK ;

PADMANABHAN, GR ;

CUNNINGHAM, GP .

ANALYTICAL CHEMISTRY, 1962, 34 (09) :1139-&

[4] PROPERTIES OF BASES IN ACETONITRILE AS SOLVENT .2. AUTOPROTOLYSIS CONSTANT OF ACETONITRILE [J].

COETZEE, JF ;

PADMANABHAN, GR .

JOURNAL OF PHYSICAL CHEMISTRY, 1962, 66 (09) :1708-&

[5]

COETZEE JF, 1967, PROGR PHYS ORG CHEM, V4, P60

[6]

COTTON FA, 1966, ADV INORG CHEM, P1041

[7] PROPERTIES OF ELECTROLYTIC SOLUTIONS .47. CONDUCTANCE OF SOME QUATERNARY AMMONIUM AND OTHER SALTS IN WATER AT LOW CONCENTRATION [J].

DAGGETT, HM ;

BAIR, EJ ;

KRAUS, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (02) :799-803

[8]

EALDEN P, 1929, Z PHYSIK CHEM A, V144, P269

[9] CONDUCTANCE OF QUATERNARY AMMONIUM HEXAFLUOROPHOSPHATES IN ACETONITRILE [J].

ELIASSAF, J ;

FUOSS, RM ;

LIND, JE .

JOURNAL OF PHYSICAL CHEMISTRY, 1963, 67 (09) :1941-&

[10] CONDUCTANCE OF SYMMETRICAL TETRAALKYLAMMONIUM HALIDES AND PICRATES IN ACETONITRILE AT 25 DEGREES [J].

EVANS, DF ;

ZAWOYSKI, C ;

KAY, RL .

JOURNAL OF PHYSICAL CHEMISTRY, 1965, 69 (11) :3878-&