EXTRACTION OF MERCURY(II) FROM HYDROCHLORIC-ACID SOLUTIONS BY ALIQUAT-336 DISSOLVED IN CHLOROFORM

被引：16

作者：

CATTRALL, RW

DAUD, H

机构：

[1] Department of Inorganic and Analytical Chemistry, La Trobe University, Bundoora

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1979年 / 41卷 / 07期

关键词：

D O I：

10.1016/0022-1902(79)80084-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The equilibrium constants for the extraction of the species HgCl3- and HgCl42- from aqueous hydrochloric acid solutions by aliquat 336 dissolved in chloroform are reported. These show that the monovalent trichloromercurate(II) species is extracted more strongly than the divalent tetrachloromercurate(II) species. This result correlates with the selectivity behaviour previously observed[1] in coated wire ion-selective electrode studies. © 1979.

引用

页码：1037 / 1039

页数：3

共 12 条

[1] BACKBENDING AND OTHER DEVIATIONS FROM IDEALITY IN EXTRACTION SYSTEMS [J].