INSITU STM STUDIES OF LEAD ELECTRODEPOSITION ON GRAPHITE SUBSTRATE

被引:29
作者
SZKLARCZYK, M
BOCKRIS, JO
机构
[1] Surface Electrochemistry Laboratory, Texas A&M University, Texas 77843-3255, College Station
关键词
D O I
10.1149/1.2086461
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Scanning tunneling microscopy (STM) was applied in solution to study the lead electrodeposition on single-crystal graphite electrode. The amount of deposited lead was varied from a few to a hundred monolayers. The atomic lattice of electrodeposited lead was observed and compared with that observed in air. The planes [111] and [100] of deposited lead crystallites were detected. The process of anodic dissolution of Pb deposit was studied by in situ STM also. During this process the changes of surface roughness were observed. © 1990, The Electrochemical Society, Inc. All rights reserved.
引用
收藏
页码:452 / 457
页数:6
相关论文
共 29 条
[1]   THEORY OF SCANNING TUNNELING MICROSCOPY METHODS AND APPROXIMATIONS [J].
BARATOFF, A .
PHYSICA B & C, 1984, 127 (1-3) :143-150
[2]   A STUDY OF GRAPHITE SURFACE WITH STM AND ELECTRONIC-STRUCTURE CALCULATIONS [J].
BATRA, IP ;
GARCIA, N ;
ROHRER, H ;
SALEMINK, H ;
STOLL, E ;
CIRACI, S .
SURFACE SCIENCE, 1987, 181 (1-2) :126-138
[3]  
BOATA G, 1987, PHYS REV LETT, V40, P887
[4]   The structure of thin films of certain metallic oxides. [J].
Bragg, WL ;
Darbyshire, JA .
TRANSACTIONS OF THE FARADAY SOCIETY, 1932, 28 :0522-0528
[5]  
COOMBIS JH, 1986, IBM J RES DEV, V30, P445
[6]   SCANNING TUNNELING MICROSCOPIC STUDIES OF PLATINUM-ELECTRODE SURFACES [J].
FAN, FRF ;
BARD, AJ .
ANALYTICAL CHEMISTRY, 1988, 60 (08) :751-758
[7]  
FINCH GI, 1952, J ELEKTRODEPOSITORS, V28
[8]  
FROLICH PK, 1926, T AM ELECTROCHEM SOC, V49, P369
[9]  
GORBUNOVA KM, 1956, 1ST C CRYST GROWTH M, P58
[10]  
HAMIN HJ, 1986, PHYS REV B, V34, P9015