SYNTHESIS AND CRYSTAL-STRUCTURE OF THE HOMOLOGOUS SERIES PBMO6X14, X=CL, BR, I

被引：33

作者：

BOSCHEN, S

KELLER, HL

机构：

[1] Kiel, Institut für Anorganische Chemie der Christian-Albrechts-Universität

来源：

ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 1992年 / 200卷 / 3-4期

关键词：

LEAD OCTA-MU-3-HALOGENO-HEXAHALOGENO-OCTAHEDRO-HEXAMOLYBDATE(II); CRYSTAL STRUCTURE; MO6X14-GROUP;

D O I：

10.1524/zkri.1992.200.3-4.305

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The compounds PbMo6X14 with X = Cl(I), Br(II), I(III) were synthesized from corresponding mixtures of lead(II) and molybdenum(II) halides. The crystal structures were determined by X-ray analyses and were refined in the cubic spacegroup Pn3BAR (no. 201, sec. setting). The cell dimensions are I: a = 12.921(1) angstrom, II: a = 13.504(2) angstrom and III: a = 14.429(2) angstrom. The structures described below are isotypic to HgMo6Cl14 although some differences are observed. Structural and crystal chemical relations will be discussed.

引用

页码：305 / 315

页数：11

共 23 条

[1] Aliev Z.G., 1981, RUSS J INORG CHEM, V26, P1060
[2] [Anonymous], 1974, INT TABLES XRAY CRYS, VIV
[3] NAMO6CL13 - CRYSTAL-CHEMISTRY OF MOLYBDENUM(II) HALIDES
BOSCHEN, S
KELLER, HL
[J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1991, 196 (1-4): : 159 - 168
[4] BOSCHEN S, 1988, THESIS KIEL
[5] STRUCTURAL AND BONDING CHARACTERIZATIONS OF MOLYBDENUM DIBROMIDE, MO6BR12.2H2O
GUGGENBE.LJ
SLEIGHT, AW
[J]. INORGANIC CHEMISTRY, 1969, 8 (10) : 2041 - &
[6] PREPARATION AND CRYSTAL-STRUCTURE OF RUBIDIUM TRIIODOPLUMBATE (II)
HAUPT, HJ
HUBER, F
PREUT, H
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1974, 408 (02): : 209 - 213
[7] CRYSTAL-STRUCTURE OF DICESIUM OCTA-MU3-CHLORO-HEXACHLORO-OCTAHEDRO-HEXA-TUNGSTATE(II) AND -MOLYBDATE(II) COMPLEXES
HEALY, PC
KEPERT, DL
TAYLOR, D
WHITE, AH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (06): : 646 - 650
[8] JOHNSON CK, 1982, ORTEP PROGRAM CRYSTA
[9] KELLER HL, 1983, THESIS KIEL
[10] REACTIONS OF (MO6X8)X4 WITH HGY2 (X,Y=C1,BR,I)
LESAAR, H
SCHAFER, H
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1971, 385 (1-2): : 65 - &

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