SYNTHESIS AND PROPERTIES OF BIS(MU-PHENYLDIAZENIDO)OCTACARBONYLDIMANGANESE

被引:8
作者
ABEL, EW
BURTON, CA
机构
[1] Department of Chemistry, The University, Exeter
关键词
D O I
10.1016/S0022-328X(00)81087-6
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Phenyldiazenidotrimethylsilane underwent reaction with bromopentacarbonylmanganese to give bis(μ-phenyldiazenido)octacarbonylmanganese. Triphenylphosphine caused fission of the phenyldiazenido bridge to form two mononuclear five coordinate complexes [Mn(CO)3N2Ph(PPh3)] and [Mn(CO)2N2Ph-(PPh3)2]. © 1979.
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页码:229 / 233
页数:5
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