SILVER-SILVER NITRATE COUPLE AS REFERENCE ELECTRODE IN ACETONITRILE

被引:83
作者
KRATOCHVIL, B
LORAH, E
GARBER, C
机构
[1] Department of Chemistry, University of Alberta, Edmonton, Alberta
关键词
D O I
10.1021/ac60282a011
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The silver-O.OlM silver nitrate couple has been investigated as a reference electrode for potentiometric measurements in acetonitrile. The thermal temperature coefficient of the standard silver-silver(l) couple in acetonitrile is estimated to be 0.9 mV/°C. The extent of silver nitrate association was measured and evaluated. The couple is reversible and its potential is relatively unaffected by those impurities commonly found in acetonitrile. © 1969, American Chemical Society. All rights reserved.
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页码:1793 / +
页数:1
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