ELECTROCHEMISTRY OF FES2

被引：46

作者：

MEYER, RE

机构：

[1] Chemistry Division, Oak Ridge National Laboratory, Oak Ridge

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1979年 / 101卷 / 01期

关键词：

D O I：

10.1016/S0022-0728(79)80079-0

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The electrochemistry of FeS2 was investigated with anodic and cathodic polarization using both scan and steady state techniques. Emphasis was placed on anodic polarization as a function of pH, solution composition, and temperature. In strongly basic solution, a semi-amorphous film was formed and a diffusion plateau approximately proportional to hydroxide concentration was observed. No visible film was formed in acid solution, and the reaction rate increased as the pH was increased. An electrochemical mechanism is proposed which explains the pH sensitivity and other observations. © 1979 Elsevier Sequoia S.A., Lausanne.

引用

页码：59 / 71

页数：13

共 23 条

[1] BAILEY LK, 1976, CAN METALL QUART, V15, P333
[2] BIEGLER T, 1976, J ELECTROANAL CHEM, V70, P265, DOI 10.1016/S0022-0728(76)80195-7
[3] BIEGLER T, 1975, J ELECTROANAL CHEM, V60, P151
[4] BIEGLER T, 1976, TRENDS ELECTROCHEMIS, P291
[5] KATO T, 1973, NIPPON KINZOKU GAKKA, V37, P529
[6] Koch D.F.A., 1975, Modern Aspects of Electrochemistry, P211
[7] KUNORI S, 1963, NIPPON KOGYO KAISHI, V79, P35
[8] Lyons D., 1968, INORGANIC SULPHUR CH
[9] MASUKO N, 1963, DENKI KAGAKU, V31, P967
[10] MCKAY DR, 1958, T AM I MIN MET ENG, V212, P301

← 1 2 3 →