MECHANISM OF REARRANGEMENT OF PLATINACYCLOBUTANES

被引：48

作者：

CASEY, CP

SCHECK, DM

SHUSTERMAN, AJ

机构：

[1] Department of Chemistry, University of Wisconsin, Madison

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 15期

关键词：

D O I：

10.1021/ja00509a032

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

No crossover products were observed when the rearrangement of dichlorobis(pyridine)(1 -phenylpropane-1,3-diyl)-platinum(lV) (la) to dichlorobis(pyridine)(2-phenylpropane-1,3-diyl)platinum(lV) (2a) was carried out in the presence of either p-tolylcyclopropane or p-methylstyrene. Preparation of dichlorobis(pyridine)(cis-l-phenylpropane-3-d1-1,3-diyl)platinum(IV) (5a) from cis-phenylcyclopropane-2-d1and rearrangement of 5a to the β-phenylplatinacyclobutane 6 both proceeded with complete retention of stereochemistry. © 1979, American Chemical Society. All rights reserved.

引用

页码：4233 / 4236

页数：4

共 23 条

[1] ISOMERIZATION IN CHEMISTRY OF PLATINACYCLOBUTANE COMPLEXES
ALESSA, RJ
PUDDEPHATT, RJ
TIPPER, CFH
THOMPSON, PJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 157 (02) : C40 - C42
[2] REACTIONS OF (DIPHENYLCARBENE)PENTACARBONYLTUNGSTEN(O) WITH ALKENES - ROLE OF METAL-CARBENE COMPLEXES IN CYCLOPROPANATION AND OLEFIN METATHESIS REACTIONS
CASEY, CP
BURKHARDT, TJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (25) : 7808 - 7809
[3] REACTIONS OF (CO)5WC(TOL)2 WITH ALKENES - MODEL FOR STRUCTURAL SELECTIVITY IN OLEFIN METATHESIS REACTION
CASEY, CP
TUINSTRA, HE
SAEMAN, MC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (02) : 608 - 609
[4] Corbin T. F., 1973, ORG SYNTH, V5, P328
[5] SUBSTITUTED STYRENES .5. REACTION OF STYRENE AND ALPHA-METHYLSTYRENE WITH DIHALOCARBENES
DALE, WJ
SWARTZENTRUBER, PE
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1959, 24 (07) : 955 - 957
[6] CONSIDERATION OF MECHANISM OF OLEFIN METATHESIS REACTION
GRUBBS, RH
BURK, PL
CARR, DD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (11) : 3265 - 3267
[7] CONSIDERATION OF MECHANISM OF METAL-CATALYZED OLEFIN METATHESIS REACTION
GRUBBS, RH
CARR, DD
HOPPIN, C
BURK, PL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (12) : 3478 - 3483
[8] GRUBBS RH, PROG INORG CHEM
[9] REACTIONS AND PROPERTIES OF SOME TRIMETHYLENEPLATINUM(IV)COMPLEXES .2. REACTIONS WITH ADDED LIGANDS
HALL, PW
PUDDEPHATT, RJ
TIPPER, CFH
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 84 (03) : 407 - 417
[10] HERRISSON JL, 1971, MAKROMOL CHEM, V141, P161

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