THE DISTRIBUTION OF CARBOXYMETHYL GROUPS IN O-(CARBOXY-METHYL)ATED (1-]3)-BETA-D-GLUCANS AND (1-]3)-ALPHA-D-GLUCANS

被引：9

作者：

UKAI, S

YOSHIDA, I

HONDA, A

NAGAI, K

KIHO, T

机构：

[1] Gifu Pharmaceutical University, Gifu, 502, Mitahora-higashi

来源：

CARBOHYDRATE RESEARCH | 1992年 / 224卷

关键词：

D O I：

10.1016/0008-6215(92)84106-3

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The distribution of the substituents in O-(carboxymethyl)ated, linear (1 --> 3)-beta-D-glucans, branched (1 --> 3)-beta-D-glucan, and (1 --> 3)-alpha-D-glucans was analyzed by g.l.c. and g.l.c.-m.s. The results indicated that the distribution of the substituents in O-(carboxymethyl)-D-glucans was characteristic of glucan type, especially at position 2 on the D-glucosyl residues, and suggested that the conformation of the D-glucans affected the O-carboxymethylation pattern.

引用

收藏

页码：201 / 208

页数：8

相关论文

共 11 条

[1] TRIPLE HELICAL STRUCTURE OF LENTINAN, A LINEAR BETA-(1-]3)-D-GLUCAN [J].

BLUHM, TL ;

SARKO, A .

CANADIAN JOURNAL OF CHEMISTRY, 1977, 55 (02) :293-299

[2]

HONDA S, 1986, IMMUNOPHARMACOLOGY, V11, P29

[3] ACID HYDROLYSIS OF MONO-HYDROXYETHYL ETHERS OF METHYL ALPHA- AND BETA-D-GLUCOPYRANOSIDE [J].

HOOK, JE ;

LINDBERG, B .

ACTA CHEMICA SCANDINAVICA, 1968, 22 (03) :921-&

[4] POLYSACCHARIDES IN FUNGI .13. (1-]3)-ALPHA-D-GLUCAN FROM AN ALKALINE EXTRACT OF AGROCYBE-CYLINDRACEA, AND ANTITUMOR-ACTIVITY OF ITS O-(CARBOXYMETHYL)ATED DERIVATIVES [J].

KIHO, T ;

YOSHIDA, I ;

NAGAI, K ;

UKAI, S ;

HARA, C .

CARBOHYDRATE RESEARCH, 1989, 189 :273-279

[5] PREPARATION AND MASS-SPECTRAL ANALYSIS OF O-HYDROXY-ETHYL DERIVATIVES OF D-GLUCOSE [J].

NAGAI, K ;

HONDA, A ;

KIHO, T ;

UKAI, S ;

TSUCHIYA, T .

CARBOHYDRATE RESEARCH, 1989, 190 (02) :165-180

[6]

OHNO N, 1988, CHEM PHARM BULL, V36, P1016

[7] POLYSACCHARIDE CONFORMATION .6. COMPUTER MODEL-BUILDING FOR LINEAR AND BRANCHED PYRANOGLYCANS - CORRELATIONS WITH BIOLOGICAL FUNCTION - PRELIMINARY ASSESSMENT OF INTER-RESIDUE FORCES IN AQUEOUS SOLUTION - FURTHER INTERPRETATION OF OPTICAL ROTATION IN TERMS OF CHAIN CONFORMATION [J].

REES, DA ;

SCOTT, WE .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1971, (03) :469-&

[8] INNER GLUCOSIDES OF ANOMERIC 2-O-(2-HYDROXYETHYL)-D-GLUCOSES [J].

ROBERTS, EJ ;

ROWLAND, SP .

CANADIAN JOURNAL OF CHEMISTRY, 1969, 47 (09) :1592-&

[9] ANTI-TUMOR ACTIVITY OF CARBOXYMETHYLGLUCANS OBTAINED BY CARBOXYMETHYLATION OF (1-]3)-BETA-D-GLUCAN FROM ALCALIGENES-FAECALIS VAR MYXOGENES IFO-13140 [J].

SASAKI, T ;

ABIKO, N ;

NITTA, K ;

TAKASUKA, N ;

SUGINO, Y .

EUROPEAN JOURNAL OF CANCER, 1979, 15 (02) :211-215

[10] GAS-LIQUID CHROMATOGRAPHY OF ACID HYDROLYSATES OF HYDROXYETHYLSTARCH AND HYDROXYETHYLCELLULOSE [J].

UKAI, S ;

HONDA, A ;

NAGAI, K ;

KIHO, T ;

TSUCHIYA, T .

JOURNAL OF CHROMATOGRAPHY, 1988, 435 (02) :374-379