PHOSPHONATE VS PHOSPHINATE ELIMINATION DURING OLEFINATION OF ALDEHYDES

被引：4

作者：

PRASHAD, M

机构：

[1] Sandoz Research Institute East Hanover

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 10期

关键词：

D O I：

10.1016/0040-4039(93)85013-M

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Olefination of aldehydes with O,O,O-triethyl n-methylmethylenephosphonophosphinate in the presence of magnesium bromide etherate and triethylamine leads to a selective elimination of the phosphonate group over the phosphinate to yield alkenyl(methyl)phosphinates in a convenient manner.

引用

页码：1585 / 1588

页数：4

共 6 条

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