THE CONCEPT OF AN EQUILIBRIUM SURFACE-APPLIED TO PARTICLE SOURCES AND CONTAMINANT DISTRIBUTIONS IN ESTUARINE SEDIMENTS

Studies have shown that many chemically-reactive contaminants become associated with fine particles in coastal waters and that the rate, pattern, and extent of contaminant accumulation within estuarine systems are extremely variable. In this paper, we briefly review our findings concerning the accumulation patterns of contaminants in several estuarine systems along the eastern coastline of the United States, and have applied a well-established concept in geology, that is ''an equilibrium profile,'' to explain the observed large variations in these patterns. We show that fine-particle deposition is the most important factor affecting contaminant accumulation in estuarine areas, and that accumulation patterns are governed by physical processes acting to establish or maintain a sediment surface in dynamic equilibrium with respect to sea level, river discharge, tidal currents, and wave activity. Net long-term particle and particle-associated contaminant accumulation are negligible in areas where the sediment surface has attained ''dynamic equilibrium'' with the hydraulic regime. Contaminant accumulation in these areas primarily occurs by the exchange of contaminant-poor sedimentary particles with contaminant-rich suspended particles during physical or biological mixing of the surface sediment. Virtually the entire estuarine particulate and contaminant load bypasses these ''equilibrium'' areas to accumulate at extremely rapid rates in relatively small areas that are temporally out of equilibrium as a result of natural processes or human activities. These relatively small areas serve as major sinks for particles from riverine and marine sources, and for biogenic carbon formed in situ within estuaries or on the inner shelf.