MOLECULAR-STRUCTURE, CONFORMATION AND VIBRATIONAL AMPLITUDES OF 1,5-HEXADIYNE (BIPROPARGYL) IN VAPOR-PHASE

被引：21

作者：

TRAETTEBERG, M

CYVIN, BN

HOPF, H

BAKKEN, P

SEIP, R

CYVIN, SJ

机构：

[1] UNIV WURZBURG,INST ORGAN CHEM,D-8700 WURZBURG,FED REP GER

[2] UNIV TRONDHEIM,DIV PHYS CHEM,NTH,N-7034 TRONDHEIM,NORWAY

[3] UNIV OSLO,DEPT CHEM,OSLO,NORWAY

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1979年 / 51卷 / 01期

关键词：

D O I：

10.1016/0022-2860(79)80271-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The molecular structure and conformation of 1,5-hexadiyne have been studied by the gas electron diffraction method. The molecules were found to exist in an anti/gauche conformational mixture, with the anti conformer very predominant (75 ± 10% anti conformer). The observed conformational composition was correlated with the magnitude of the gauche dihedral angle and the mean vibrational amplitudes of the C1C5 and C1C6 distances of the anti conformer. © 1979.

引用

页码：77 / 85

页数：9

共 15 条

[1] TRANSITION-METAL CATALYZED ACETYLENE CYCLIZATIONS - 4,5-BIS(TRIMETHYLSILYL)BENZOCYCLOBUTENE, A HIGHLY STRAINED, VERSATILE SYNTHETIC INTERMEDIATE [J].