FUNCTIONALIZATION OF SOLUBLE POLYMERS .1. REPLACEMENT OF THE HYDROXYL-GROUPS OF POLY(OXYETHYLENE) BY AMINO-GROUPS

被引:27
作者
GECKELER, K
机构
[1] Institut für Organische Chemie der Universität, Tübingen
关键词
D O I
10.1007/BF00284414
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In a first example of the functionalization of soluble polymers the conversion of the hydroxyl groups of poly(oxyethylene) into primary amino groups has been studied. Starting from poly(oxyethylene), the preparation of the diphthalimido derivative via the disodium salt is described. Prom this regiospecific functionalized polymer the di(aminoethyl) poly(oxyethylene), which exhibits excellent solubility properties, can be obtained by polymeranalogous hydrazinolysis. © 1979 Springer-Verlag.
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页码:427 / 431
页数:5
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