HETEROCYCLIC CYCLOPROPARENES - APPROACHES TO THE CYCLOPROPA[C]THIOPHENE SYSTEM

被引：14

作者：

ANTHONY, IJ ^{[1
]}

KANG, YB ^{[1
]}

WEGE, D ^{[1
]}

机构：

[1] UNIV WESTERN AUSTRALIA,DEPT ORGAN CHEM,NEDLANDS,WA 6009,AUSTRALIA

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 09期

关键词：

D O I：

10.1016/S0040-4039(00)88795-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dehydrochlorination of 6,6-dichloro-3-thiabicyclo[3.1.0]hexane generates a cyclopro, pene which can be trapped with t-BuOH or furan, while 1,5-dibromo-6,6-dimethyl-3-thiabicyclo[3.1.0]hexane undergoes dehydrobromination to afford the highly reactive 4,4-dimethyl-4H-cyclopropa[c]thiophene, which was trapped with isobenzofuran. © 1990.

引用

页码：1315 / 1318

页数：4

共 14 条

[1] HETEROCYCLIC CYCLOPROPARENES - 5H-CYCLOPROP[F]ISOBENZOFURAN AND 5H-CYCLOPROPA[F][2]BENZOTHIOPHENE [J].

ANTHONY, IJ ;

WEGE, D .

TETRAHEDRON LETTERS, 1987, 28 (36) :4217-4220

[2] SYNTHESIS AND STRUCTURE OF A CYCLOPROPAPYRIDINE [J].

BAMBAL, R ;

FRITZ, H ;

RIHS, G ;

TSCHAMBER, T ;

STREITH, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (07) :668-669

[3] SYNTHESIS AND CHEMISTRY OF BENZOCYCLOPROPENES [J].

BILLUPS, WE .

ACCOUNTS OF CHEMICAL RESEARCH, 1978, 11 (06) :245-251

[4] CYCLOPROPARENES [J].

BILLUPS, WE ;

RODIN, WA ;

HALEY, MM .

TETRAHEDRON, 1988, 44 (05) :1305-1338

[5] STUDIES IN THE CYCLOPROPARENE SERIES - APPROACHES TO CYCLOPROPAHETEROARENES [J].

BUCKLAND, SJ ;

HALTON, B ;

STANOVNIK, B .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1987, 40 (12) :2037-2047

[6] TOTAL SYNTHESIS OF ANALOGS OF THE BETA-LACTAM ANTIBIOTICS .2. ISOPENAM-3-CARBOXYLATES AND THEIR 2,2-DIOXIDES [J].

CRACKETT, PH ;

PANT, CM ;

STOODLEY, RJ .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1984, (12) :2785-2793

[7] VAPOR-PHASE DEHYDROHALOGENATION OF ALKYL-HALIDES ON SILICA-SUPPORTED POTASSIUM TERT-BUTYLATE - SYNTHESIS FOR HIGHLY STRAINED CYCLES [J].

DENIS, JM ;

NIAMAYOUA, R ;

VATA, M ;

LABLACHECOMBIER, A .

TETRAHEDRON LETTERS, 1980, 21 (06) :515-518

[8] ELECTROPHILIC CYCLOPROPENES .2. SYNTHESIS OF 3,3-DIMETHYLPYRAZOLENINES VIA PHOTOLYSIS [J].

DIETRICHBUCHECKER, C ;

FRANCKNEUMANN, M .

TETRAHEDRON, 1977, 33 (07) :751-755

[9] THE CYCLOPROPARENES [J].

HALTON, B .

INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1980, 19 (03) :349-364

[10] BENZOCYCLOPROPENES [J].

HALTON, B .

CHEMICAL REVIEWS, 1973, 73 (02) :113-126

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